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dc.contributor.authorLeontiev, A. V.-
dc.contributor.authorЛеонтьев, А. В.-
dc.contributor.authorMomotova, D. S.-
dc.contributor.authorМомотова, Д. С.-
dc.identifier.citationRatmanova, N.K., Andreev, I.A., Leontiev, A.V., Momotova, D., Novoselov, A.M., Ivanova, O.A., Trushkov, I.V. Strategic approaches to the synthesis of pyrrolizidine and indolizidine alkaloids // Tetrahedron. - 2020. - Номер статьи 131031ru
dc.description.abstractThe principal methods for the synthesis of pyrrolizidine and indolizidine alkaloids and their unnatural analogs are described. Six main “strategic” approaches in regard to a key step forming azabicyclic skeleton are identified. Namely, these are: 1) hydrogenation of the corresponding heteroaromatic compounds; 2) various condensations of carbonyl compounds and their surrogates; 3) cycloaddition reactions; 4) sigmatropic shifts and other rearrangements; 5) transition metal-mediated cyclizations (including the ring-closing alkene metathesis); and 6) radical processes. Such important issues, as retrosynthetic analysis, chiral pool synthesis, and chiral auxiliaries, are also discussedru
dc.publisherElsevier Ltdru
dc.subjectIndolizidine alkaloidsru
dc.subjectOrganic synthesis strategiesru
dc.subjectPyrrolizidine alkaloidsru
dc.subjectRetrosynthetic analysisru
dc.titleStrategic approaches to the synthesis of pyrrolizidine and indolizidine alkaloidsru
vkr.instИнститут математики и естественных наукru
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