Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12258/15578
Title: Features of IR reflection spectra of β-Tl1-xCuxInS2single crystals (0 ≤ X ≤ 0.015)
Authors: Sysoev, I. A.
Сысоев, И. А.
Keywords: Atomsy;Thallium;Copper;Copper metallograph;Lead metallography;Single crystals;Thallium metallography
Issue Date: 2021
Publisher: IOP Publishing Ltd
Citation: Matiyev, A.Kh., Uspazhiev, R.T., Gachaev, A.M., Sysoev, I.A., Khamkhoev, B.M., Matieva, T.Ah., Chapanov, K.S.-G., Bagov, A.M. Features of IR reflection spectra of β-Tl1-xCuxInS2single crystals (0 ≤ X ≤ 0.015) // Journal of Physics: Conference Series. - 2021. - Volume 1753. - Issue 1. - Номер статьи 012077
Series/Report no.: Journal of Physics: Conference Series
Abstract: The method of long-wave spectroscopy made it possible to study the IR reflection spectra of layered single crystals β-Tl1-xCuxInS2 (0≤X≤0.015) in in the frequency range of 40-500 cm-1 and the temperature range of 84 300 K. It was shown that partial substitution of thallium atoms with copper atoms leads to a decrease in the frequencies of the corresponding oscillations in the frequency range of 40-500 cm-1 and does not lead (at these concentrations) to local oscillations. It was found that solid solutions β-Tl1-xCuxInS2 (X=0 ÷ 0.015) exhibit the characteristic single-mode behavior. It was shown that partial substitution of thallium atoms with copper atoms in single crystals β-Tl1-xCuxInS2 (X = 0.005; 0.010; 0.015) weakens the ionic bond in Tl-S, as a result of which the frequencies of "internal"oscillations shift towards low temperatures
URI: http://hdl.handle.net/20.500.12258/15578
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