Please use this identifier to cite or link to this item: https://dspace.ncfu.ru/handle/20.500.12258/18091
Title: 1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties
Authors: Demidov, O. P.
Демидов, О. П.
Borovlev, I. V.
Боровлев, И. В.
Keywords: 1,3,7-Triazapyrene-based ortho-carborane fluorophores;Molecular electronics;Organic luminophores
Issue Date: 2021
Publisher: American Chemical Society
Citation: Smyshliaeva, L. A.; Varaksin, M. V.; Fomina, E. I.; Medvedeva M. V.; Svalova T. S.; Kozitsina A. N.; Demidov, O. P.; Borovlev, I V .; Mensch C.; Mampuys P.; Maes B. U. W.; Charushin, V. N.; Chupakhin, O. N. 1,3,7-triazapyrene-based ortho-carborane fluorophores: convenient synthesis, theoretical studies, and aggregation-induced emission properties // Organometallics. - 2021. - Volume 40. - Issue 16. - Page 2792-2807
Series/Report no.: Organometallics
Abstract: A convenient transition-metal-free approach, based on nucleophilic substitution of hydrogen (SNH), for consecutive regioselective C-H functionalization of 1,3,7-triazapyrene scaffolds with carboranyllithium and phenyllithium is reported. The theoretical calculations disclosed highlight key features in the regioselectivity and mechanism of the investigated SNH transformations. The novel 1,3,7-triazapyrene-based ortho-carboranes obtained have large potential in the field of molecular electronics as organic luminophores, which are characterized by the aggregation-induced emission and dual-emission effects
URI: http://hdl.handle.net/20.500.12258/18091
Appears in Collections:Статьи, проиндексированные в SCOPUS, WOS

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