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Title: | Nitrovinylindoles as Heterotrienes: Electrocyclic Cyclization En Route to β-Carbolines: Total Synthesis of Alkaloids Norharmane, Harmane, and Eudistomin N |
Authors: | Aksenov, N. A. Аксенов, Н. А. Arutiunov, N. A. Арутюнов, Н. А. Aksenov, A. V. Аксенов, А. В. Aksenova, I. V. Аксенова, И. В. Aleksandrova, E. V. Александрова, Е. В. Aksenov, D. A. Аксенов, Д. А. Rubin, M. A. Рубин, М. А. |
Keywords: | Alkaloids;Biological products;Carbolines;Cyclization;Harmine |
Issue Date: | 2022 |
Publisher: | American Chemical Society |
Citation: | Aksenov, N.A., Arutiunov, N.A., Aksenov, A.V., Aksenova, I.V., Aleksandrova, E.V., Aksenov, D.A., Rubin, M. Nitrovinylindoles as Heterotrienes: Electrocyclic Cyclization En Route to β-Carbolines: Total Synthesis of Alkaloids Norharmane, Harmane, and Eudistomin N // Organic Letters. - 2022. - Volume 24. - Issue 39. - Pages 7062-7066. - DOI10.1021/acs.orglett.2c02483 |
Series/Report no.: | Organic Letters |
Abstract: | Unusual cascade transformation was developed involving microwave assisted electrocyclic cyclization of aci (alkylideneazinic acid) forms of nitrovinylindoles acting as heterotrienes. Subsequent one-pot reduction allowed for efficient access to β-carbolines, including several natural products, alkaloids norharmane, harmane and eudistomin N. |
URI: | http://hdl.handle.net/20.500.12258/21932 |
Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
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scopusresults 2371 .pdf Restricted Access | 64.29 kB | Adobe PDF | View/Open | |
WoS 1480 .pdf Restricted Access | 113.58 kB | Adobe PDF | View/Open |
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