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Title: Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides
Authors: Dotsenko, V. V.
Доценко, В. В.
Strelkov, V. D.
Стрелков, В. Д.
Aksenov, N. A.
Аксенов, Н. А.
Aksenova, I. V.
Аксенова, И. В.
Keywords: Growth-regulating activity;Antidote activity against 2,4-D;Thioamides;Oxidative dimerization;Electrochemical synthesis;1,2,4-thiadiazoles
Issue Date: 2022
Citation: Osminin, V.I., Mironenko, A.A., Dahno, P.G., Nazarenko, M.A., Oflidi, A.I., Dotsenko, V.V., Strelkov, V.D., Aksenov, N.A., Aksenova, I.V. Electrochemical Oxidation of 3-Aryl-2-cyanothioacrylamides // Russian Journal of General Chemistry. - 2022. - 92 (11), pp. 2235-2245. - DOI: 10.1134/S1070363222110068
Series/Report no.: Russian Journal of General Chemistry
Abstract: Electrochemical oxidation of (Е)-3-aryl-2-cyanoprop-2-enethioamides in a undivided cell in the presence of KBr in an aqueous or aqueous-organic medium has led to the formation of (2Е,2′E)-2,2′-(1,2,4-thiadiazole-3,5-diyl)bis[3-arylacrylonitriles] in 37–76% yield. A plausible reaction mechanism has been discussed. In laboratory experiments, (2E,2′E)-2,2′-(1,2,4-thiadiazol-3,5-diyl)bis[3-(4-methoxyphenyl)acrylonitrile] has revealed pronounced antidote effect against herbicide 2,4-D on sunflower seedlings and no pronounced growth-regulating properties.
Appears in Collections:Статьи, проиндексированные в SCOPUS, WOS

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