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Title: | Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones |
Authors: | Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. |
Keywords: | Aldehyde derivative;Ketone derivative;Stannic chloride;Oxidative coupling |
Issue Date: | 2017 |
Publisher: | Royal Society of Chemistry |
Citation: | Levashov, A.S., Aksenov, N.A., Aksenova, I.V., Konshin, V.V. Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones // New Journal of Chemistry. - 2017. - Volume 41. - Issue 16. - Pages 8297-8304 |
Series/Report no.: | New Journal of Chemistry |
Abstract: | The reaction of tetraalkynyltin with aldehydes was studied for the first time. The reaction was shown to proceed as a tandem process of nucleophilic addition of tin acetylide to aldehyde followed by Oppenauer-type oxidation of produced tin alcoholates, and may be used as a convenient one-pot approach to acetylenic ketones. The advantages and limitations of the proposed method are discussed |
URI: | https://www.scopus.com/record/display.uri?eid=2-s2.0-85027030617&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=1af4e03e943ebe5b20c0bfa6c2ca02b9&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Oxidative+coupling+of+tetraalkynyltin+with+aldehydes+leading+to+alkynyl+ketones%29&relpos=1&citeCnt=3&searchTerm= http://hdl.handle.net/20.500.12258/2974 |
Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
Files in This Item:
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scopusresults 266 .pdf Restricted Access | 61.79 kB | Adobe PDF | View/Open | |
WoS 141 .pdf Restricted Access | 1.63 MB | Adobe PDF | View/Open |
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