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Title: Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
Authors: Aksenov, N. A.
Аксенов, Н. А.
Aksenova, I. V.
Аксенова, И. В.
Keywords: Aldehyde derivative;Ketone derivative;Stannic chloride;Oxidative coupling
Issue Date: 2017
Publisher: Royal Society of Chemistry
Citation: Levashov, A.S., Aksenov, N.A., Aksenova, I.V., Konshin, V.V. Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones // New Journal of Chemistry. - 2017. - Volume 41. - Issue 16. - Pages 8297-8304
Series/Report no.: New Journal of Chemistry
Abstract: The reaction of tetraalkynyltin with aldehydes was studied for the first time. The reaction was shown to proceed as a tandem process of nucleophilic addition of tin acetylide to aldehyde followed by Oppenauer-type oxidation of produced tin alcoholates, and may be used as a convenient one-pot approach to acetylenic ketones. The advantages and limitations of the proposed method are discussed
Appears in Collections:Статьи, проиндексированные в SCOPUS, WOS

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