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Title: Direct and facile synthesis of 9-aminoacridine and acridin-9-yl-ureas
Authors: Borovlev, I. V.
Боровлев, И. В.
Demidov, O. P.
Демидов, О. П.
Amangasieva, G. A.
Амангазиева, Г. А.
Avakyan, E. K.
Авакян, Е. К.
Keywords: Facile synthesis;Direct synthesis;9-aminoacridine;Acridin-9-yl-ureas
Issue Date: 2016
Publisher: Elsevier Ltd
Citation: Borovlev, I.V., Demidov, O.P., Amangasieva, G.A., Avakyan, E.K. Direct and facile synthesis of 9-aminoacridine and acridin-9-yl-ureas // Tetrahedron Letters. - 2016. - Volume 57. - Issue 32. - Pages 3608-3611
Series/Report no.: Tetrahedron Letters
Abstract: The ability of urea anions to react as nucleophiles with acridine has been investigated. An effective SNH synthesis of 9-aminoacridine was developed using the urea/NaH/DMSO system. However, when mono substituted ureas containing bulky substituents or 1,1-dialkyl substituted ureas were used, products of the SNH reaction of alkyl carbamoyl amination were obtained. Single crystal structure and the tautomerism of selected compound were studied
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