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Title: | Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions |
Authors: | Borovlev, I. V. Боровлев, И. В. Demidov, O. P. Демидов, О. П. Kurnosova, N. A. Курносова, Н. А. Avakyan, E. K. Авакян, Е. К. Amangasieva, G. A. Амангазиева, Г. А. |
Keywords: | 1,3,7-triazapyrene;Derivatives by SNH and SNAr reactions |
Issue Date: | 2015 |
Publisher: | Maik Nauka Publishing / Springer SBM |
Citation: | Borovlev, I.V., Demidov, O.P., Kurnosova, N.A., Avakyan, E.K., Amangazieva, G.A. Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions // Russian Journal of Organic Chemistry. - 2015. - Volume 51. - Issue 10. - Pages 1438-1443 |
Series/Report no.: | Russian Journal of Organic Chemistry |
Abstract: | 1,3,7-Triazapyrene reacts with amino alcohols in aqueous medium in the presence of K3Fe(CN)6 or in the system DMSO-KOH-O2 via oxidative nucleophilic substitution of hydrogen to give the corresponding 6-hydroxyalkylamino derivatives. The reaction of 1,3,7-triazapyrene with sodium amide in DMSO at room temperature yields 1,3,7-triazapyren-6-amine. N-Alkyl-8-methoxy-1,3,7-triazapyren-6-amines or N,N'-dialkyl- 1,3,7-triazapyrene-6,8-diamines are formed in reactions of 6,8-dimethoxy-1,3,7-triazapyrene with alkylamines or amino alcohols in DMSO, depending on the conditions |
URI: | https://www.scopus.com/record/display.uri?eid=2-s2.0-84947425049&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=dc7f8c6f40c1112203ece798567bdeb2&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=10&citeCnt=0&searchTerm= http://hdl.handle.net/20.500.12258/3691 |
Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
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scopusresults 657 .pdf Restricted Access | 62.92 kB | Adobe PDF | View/Open | |
WoS 428 .pdf Restricted Access | 299.17 kB | Adobe PDF | View/Open |
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