Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12258/3691
Title: Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions
Authors: Borovlev, I. V.
Боровлев, И. В.
Demidov, O. P.
Демидов, О. П.
Kurnosova, N. A.
Курносова, Н. А.
Avakyan, E. K.
Авакян, Е. К.
Amangasieva, G. A.
Амангазиева, Г. А.
Keywords: 1,3,7-triazapyrene;Derivatives by SNH and SNAr reactions
Issue Date: 2015
Publisher: Maik Nauka Publishing / Springer SBM
Citation: Borovlev, I.V., Demidov, O.P., Kurnosova, N.A., Avakyan, E.K., Amangazieva, G.A. Synthesis of heterofunctional 1,3,7-triazapyrene derivatives by SNH and SNAr reactions // Russian Journal of Organic Chemistry. - 2015. - Volume 51. - Issue 10. - Pages 1438-1443
Series/Report no.: Russian Journal of Organic Chemistry
Abstract: 1,3,7-Triazapyrene reacts with amino alcohols in aqueous medium in the presence of K3Fe(CN)6 or in the system DMSO-KOH-O2 via oxidative nucleophilic substitution of hydrogen to give the corresponding 6-hydroxyalkylamino derivatives. The reaction of 1,3,7-triazapyrene with sodium amide in DMSO at room temperature yields 1,3,7-triazapyren-6-amine. N-Alkyl-8-methoxy-1,3,7-triazapyren-6-amines or N,N'-dialkyl- 1,3,7-triazapyrene-6,8-diamines are formed in reactions of 6,8-dimethoxy-1,3,7-triazapyrene with alkylamines or amino alcohols in DMSO, depending on the conditions
URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-84947425049&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=dc7f8c6f40c1112203ece798567bdeb2&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=10&citeCnt=0&searchTerm=
http://hdl.handle.net/20.500.12258/3691
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