Synthesis of 1,5-dioxocanes via the two-fold C-O bond forming nucleophilic 4 + 4-cyclodimerization of cycloprop-2-en-1-ylmethanols

Please use this identifier to cite or link to this item: https://dspace.ncfu.ru/handle/20.500.12258/3699

Title:	Synthesis of 1,5-dioxocanes via the two-fold C-O bond forming nucleophilic 4 + 4-cyclodimerization of cycloprop-2-en-1-ylmethanols
Authors:	Rubin, M. A. Рубин, М. А.
Keywords:	Alkoxides;Bond forming;Cyclodimerization;Cyclopropenes;Diastereoselective;Double bonds;Strain release;Scaffolds
Issue Date:	2015
Publisher:	Royal Society of Chemistry
Citation:	Edwards, A., Bennin, T., Rubina, M., Rubin, M. Synthesis of 1,5-dioxocanes via the two-fold C-O bond forming nucleophilic 4 + 4-cyclodimerization of cycloprop-2-en-1-ylmethanols // RSC Advances. - 2015. - Volume 5. - Issue 88. - Pages 71849-71853
Series/Report no.:	RSC Advances
Abstract:	An efficient [4 + 4] cyclodimerization of cyclopropenemethanols operating via a two-fold strain release-driven addition of alkoxides across the double bond of cyclopropenes was investigated. This chemo- and diastereoselective transformation provided previously unknown 2,7-dioxatricyclo[7.1.0.04,6]decane scaffolds
URI:	https://www.scopus.com/record/display.uri?eid=2-s2.0-84940491140&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=dc7f8c6f40c1112203ece798567bdeb2&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=18&citeCnt=8&searchTerm= http://hdl.handle.net/20.500.12258/3699
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