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http://hdl.handle.net/20.500.12258/3723
Title: | Amides of 1,3,7-triazapyrene series: synthesis by nucleophilic substitution of alkoxy groups |
Authors: | Borovlev, I. V. Боровлев, И. В. Demidov, O. P. Демидов, О. П. Kurnosova, N. A. Курносова, Н. А. Amangasieva, G. A. Амангазиева, Г. А. Avakyan, E. K. Авакян, Е. К. |
Keywords: | 6,8-dialkoxy-1,3,7-triazapyrenes;Ipso substitution of alkoxy groups;Nucleophilic amidation;Tandem SNAr ipso -SN2 reactions |
Issue Date: | 2015 |
Publisher: | Springer New York LLC |
Citation: | Borovlev, I.V., Demidov, O.P., Kurnosova, N.A., Amangazieva, G.A., Avakyan, E.K. Amides of 1,3,7-triazapyrene series: Synthesis by nucleophilic substitution of alkoxy groups // Chemistry of Heterocyclic Compounds. - 2015. - Volume 51. - Issue 4. - Pages 334-339 |
Series/Report no.: | Chemistry of Heterocyclic Compounds |
Abstract: | The treatment of 6,8-dialkoxy-1,3,7-triazapyrenes with sodium acylamides in DMSO at room temperature resulted in ipso substitution of one alkoxy group with amide group, giving 8-acylamino-6-alkoxy-1,3,7-triazapyrenes. The reaction at 65-70°C proceeded as a tandem SNAr ipso -SN2 process, leading to the formation of 8-acylamino-6-oxo-6,7-dihydro-1,3,7-triazapyrenes |
URI: | https://www.scopus.com/record/display.uri?eid=2-s2.0-84938963778&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=fe656e0c7517dbc25228b3d577bd000c&sot=afnl&sdt=cl&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=36&citeCnt=3&searchTerm= http://hdl.handle.net/20.500.12258/3723 |
Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
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scopusresults 689 .pdf Restricted Access | 63.09 kB | Adobe PDF | View/Open | |
WoS 448 .pdf Restricted Access | 644.91 kB | Adobe PDF | View/Open |
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