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Title: Preparation of stereodefined 2-(3-Oxoindolin-2-yl)-2-arylacetonitriles via one-pot reaction of indoles with nitroalkenes
Authors: Aksenov, A. V.
Аксенов, А. В.
Aksenov, D. A.
Аксенов, Д. А.
Aksenov, N. A.
Аксенов, Н. А.
Aleksandrova, E. V.
Александрова, Е. В.
Rubin, M. A.
Рубин, М. А.
Keywords: Chemistry;Diastereoselective;Nitroalkenes;One-pot reaction;Oxazoline ring;Phosphorous acid;Organic compounds
Issue Date: 2019
Publisher: American Chemical Society
Citation: Aksenov, A.V., Aksenov, D.A., Aksenov, N.A., Aleksandrova, E.V., Rubin, M. Preparation of Stereodefined 2-(3-Oxoindolin-2-yl)-2-Arylacetonitriles via One-Pot Reaction of Indoles with Nitroalkenes // Journal of Organic Chemistry. - 2019. - Volume 84. - Issue 19. - Pages 12420-12429
Series/Report no.: Journal of Organic Chemistry
Abstract: Recently discovered reactivity of nitrostyrenes in phosphorous acid to facilitate the diastereoselective [4 + 1]-cycloaddition of indoles in combination with unusual oxazoline ring cleavage and subsequent 1,2-alkyl shift afforded stereochemically defined 2-(3-oxoindolin-2-yl)-2-arylacetonitriles as sole products
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