Репозиторий научных и учебно-методических публикаций
Северо-Кавказский федеральный университет
Please use this identifier to cite or link to this item:
https://dspace.ncfu.ru/handle/123456789/28759| Title: | Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid |
| Authors: | Aksenov, A. V. Аксенов, А. В. Grishin, I. Y. Гришин, И. Ю. Aksenov, D. A. Аксенов, Д. А. Grishin, Y. I. Гришин, Ю. И. Aksenova, I. V. Аксенова, И. В. Aksenov, N. A. Аксенов, Н. А. |
| Keywords: | Acylamination;Polyphosphoric acid;Aliphatic nitro compounds;Anilides;Beckmann rearrangement;Benzamides |
| Issue Date: | 2024 |
| Publisher: | Springer |
| Citation: | Aksenov, A.V., Grishin, I.Y., Aksenov, D.A., Grishin, Y.I., Aksenova, I.V., Aksenov, N.A. Effects of the structure of primary nitroalkanes and reaction conditions on the selectivity of acylamination of arenes in polyphosphoric acid // Russian Chemical Bulletin. - 2024. - 73 (6). - pp. 1612-1622. - DOI: 10.1007/s11172-024-4277-8 |
| Series/Report no.: | Russian Chemical Bulletin |
| Abstract: | The mechanism of acylamination of arenes with nitroalkanes in polyphosphoric acid has been clarified. The influence of the concentration of polyphosphoric acid, the structure of the starting compounds, and temperature on the result of the Beckmann rearrangement, which makes it possible to shift the reaction towards either benzamides or anilides, has been assessed. |
| URI: | https://dspace.ncfu.ru/handle/123456789/28759 |
| Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| scopusresults 3153 .pdf Restricted Access | 131.95 kB | Adobe PDF | View/Open | |
| WoS 1924 .pdf Restricted Access | 120.81 kB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.