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Please use this identifier to cite or link to this item: https://dspace.ncfu.ru/handle/20.500.12258/19744
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dc.contributor.authorDemidov, O. P.-
dc.contributor.authorДемидов, О. П.-
dc.date.accessioned2022-06-21T14:46:37Z-
dc.date.available2022-06-21T14:46:37Z-
dc.date.issued2022-
dc.identifier.citationSemenova, I. А., Osyanin, V. А., Demidov, O. P., Osipov, D. V. Opening of the furan ring of 3-Nitrobenzofurans by the action of carbonyl-stabilized sulfonium ylides // Chemistry of Heterocyclic Compounds. - 2022. - Том 58. - Выпуск 4-5. - Стр.: 251 - 254. - DOI10.1007/s10593-022-03079-6ru
dc.identifier.urihttp://hdl.handle.net/20.500.12258/19744-
dc.description.abstractUpon treatment of 3-nitrobenzofurans with dimethylphenacylsulfonium salts in the presence of a base, the opening of the furan ring to form (E)-1-aryl-2-(dimethylsulfonio)-4-nitro-1-oxobut-3-en-2-ides takes place. The mechanism of nucleophilic dearomatization of 3-nitrobenzofurans involves consecutive carbo- and retro-oxa-Michael reactions. The reaction illustrates the high propensity of 3-nitrobenzofurans for ring opening.ru
dc.language.isoenru
dc.publisherSpringerru
dc.relation.ispartofseriesChemistry of Heterocyclic Compounds-
dc.subject3-nitrobenzofuransru
dc.subjectDimethylphenacylsulfonium saltsru
dc.subjectMichael reactionru
dc.subjectNucleophilic dearomatizationru
dc.subjectSulfur ylidesru
dc.titleOpening of the furan ring of 3-Nitrobenzofurans by the action of carbonyl-stabilized sulfonium ylidesru
dc.typeСтатьяru
vkr.instХимико-фармацевтический факультетru
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