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Title: | SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline |
Authors: | Avakyan, E. K. Авакян, Е. К. Borovleva, A. A. Боровлева, А. А. Pobedinskaya, D. Y. Побединская, Д. Ю. Demidov, O. P. Демидов, О. П. Ermolenko, A. P. Ермоленко, А. П. Larin, A. N. Ларин, А. Н. Borovlev, I. V. Боровлев, И. В. |
Keywords: | Heterocycles;SNH methodology;Metal-free C–N bond formation;5-nitroisoquinoline;Redox process;Oxidative SNH amidation;SNH dialkylcarbamoylamination;Regioselectivity |
Issue Date: | 2022 |
Citation: | Avakyan, E.K., Borovleva, A.A., Pobedinskaya, D.Y., Demidov, O.P., Ermolenko, A.P., Larin, A.N., Borovlev, I.V. SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline // Molecules. - 2022. - 27 (22), статья № 7862. - DOI: 10.3390/molecules27227862 |
Series/Report no.: | Molecules |
Abstract: | For the first time, amides and ureas based on both 5-nitroisoquinoline and 5-nitrosoisoquinoline were obtained by direct nucleophilic substitution of hydrogen in the 5-nitroisoquinoline molecule. In the case of urea and monosubstituted ureas, only 5-nitrosoisoquinoline-6-amine is formed under anhy- drous conditions. |
URI: | http://hdl.handle.net/20.500.12258/22264 |
Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
Files in This Item:
File | Description | Size | Format | |
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scopusresults 2425 .pdf Restricted Access | 2.05 MB | Adobe PDF | View/Open | |
WoS 1505 .pdf Restricted Access | 114.42 kB | Adobe PDF | View/Open |
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