Please use this identifier to cite or link to this item: https://dspace.ncfu.ru/handle/20.500.12258/22264
Title: SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline
Authors: Avakyan, E. K.
Авакян, Е. К.
Borovleva, A. A.
Боровлева, А. А.
Pobedinskaya, D. Y.
Побединская, Д. Ю.
Demidov, O. P.
Демидов, О. П.
Ermolenko, A. P.
Ермоленко, А. П.
Larin, A. N.
Ларин, А. Н.
Borovlev, I. V.
Боровлев, И. В.
Keywords: Heterocycles;SNH methodology;Metal-free C–N bond formation;5-nitroisoquinoline;Redox process;Oxidative SNH amidation;SNH dialkylcarbamoylamination;Regioselectivity
Issue Date: 2022
Citation: Avakyan, E.K., Borovleva, A.A., Pobedinskaya, D.Y., Demidov, O.P., Ermolenko, A.P., Larin, A.N., Borovlev, I.V. SNH Amidation of 5-Nitroisoquinoline: Access to Nitro- and Nitroso Derivatives of Amides and Ureas on the Basis of Isoquinoline // Molecules. - 2022. - 27 (22), статья № 7862. - DOI: 10.3390/molecules27227862
Series/Report no.: Molecules
Abstract: For the first time, amides and ureas based on both 5-nitroisoquinoline and 5-nitrosoisoquinoline were obtained by direct nucleophilic substitution of hydrogen in the 5-nitroisoquinoline molecule. In the case of urea and monosubstituted ureas, only 5-nitrosoisoquinoline-6-amine is formed under anhy- drous conditions.
URI: http://hdl.handle.net/20.500.12258/22264
Appears in Collections:Статьи, проиндексированные в SCOPUS, WOS

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