Please use this identifier to cite or link to this item: https://dspace.ncfu.ru/handle/20.500.12258/23806
Title: A Diastereoselective Assembly of Tetralone Derivatives via a Tandem Michael Reaction and ipso-Substitution of the Nitro Group
Authors: Aksenov, N. A.
Аксенов, Н. А.
Aksenov, D. A.
Аксенов, Д. А.
Ganusenko, D. D.
Ганусенко, Д. Д.
Kurenkov, I. A.
Куренков, И. А.
Aksenov, A. V.
Аксенов, А. В.
Keywords: Tandem Michael reaction;Ipso-substitution of the nitro group;Tetralone derivatives
Issue Date: 2023
Citation: Aksenov, N.A., Aksenov, D.A., Ganusenko, D.D., Kurenkov, I.A., Aksenov, A.V. A Diastereoselective Assembly of Tetralone Derivatives via a Tandem Michael Reaction and ipso-Substitution of the Nitro Group // Journal of Organic Chemistry. - 2023. - 88(9), pp, 5639–5651. - DOI: 10.1021/acs.joc.3c00134
Series/Report no.: Journal of Organic Chemistry
Abstract: A highly diastereoselective tandem reaction of 2'-nitrochalcones is reported, involving Michael addition and a subsequent ipso-substitution of the nitro group to produce 1-tetralones with two contiguous chiral centers. A related annulation reaction of 2'-nitrochalcones with potassium cyanide affording 1-indanones with a C3-quaternary chiral center is also demonstrated.
URI: http://hdl.handle.net/20.500.12258/23806
Appears in Collections:Статьи, проиндексированные в SCOPUS, WOS

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