Репозиторий научных и учебно-методических публикаций
Северо-Кавказский федеральный университет
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https://dspace.ncfu.ru/handle/20.500.12258/23806| Title: | A Diastereoselective Assembly of Tetralone Derivatives via a Tandem Michael Reaction and ipso-Substitution of the Nitro Group |
| Authors: | Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Ganusenko, D. D. Ганусенко, Д. Д. Kurenkov, I. A. Куренков, И. А. Aksenov, A. V. Аксенов, А. В. |
| Keywords: | Tandem Michael reaction;Ipso-substitution of the nitro group;Tetralone derivatives |
| Issue Date: | 2023 |
| Citation: | Aksenov, N.A., Aksenov, D.A., Ganusenko, D.D., Kurenkov, I.A., Aksenov, A.V. A Diastereoselective Assembly of Tetralone Derivatives via a Tandem Michael Reaction and ipso-Substitution of the Nitro Group // Journal of Organic Chemistry. - 2023. - 88(9), pp, 5639–5651. - DOI: 10.1021/acs.joc.3c00134 |
| Series/Report no.: | Journal of Organic Chemistry |
| Abstract: | A highly diastereoselective tandem reaction of 2'-nitrochalcones is reported, involving Michael addition and a subsequent ipso-substitution of the nitro group to produce 1-tetralones with two contiguous chiral centers. A related annulation reaction of 2'-nitrochalcones with potassium cyanide affording 1-indanones with a C3-quaternary chiral center is also demonstrated. |
| URI: | http://hdl.handle.net/20.500.12258/23806 |
| Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| WoS 1652 .pdf Restricted Access | 114.9 kB | Adobe PDF | View/Open | |
| scopusresults 2614 .pdf Restricted Access | 132.65 kB | Adobe PDF | View/Open |
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