Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12258/2446
Title: Unexpected cyclization of 2-(2-aminophenyl)indoles with nitroalkenes to furnish indolo[3,2-: C] quinolines
Authors: Aksenov, A. V.
Аксенов, А. В.
Aksenov, D. A.
Аксенов, Д. А.
Griaznov, G. D.
Грязнов, Г. Д.
Aksenov, N. A.
Аксенов, Н. А.
Rubin, M. A.
Рубин, М. А.
Keywords: Positive ions;CDK inhibitors;Mechanistic pathways;Mediated reactions;Nitroalkenes;Polyphosphoric acids;Synthetic study;Chemistry
Issue Date: 2018
Publisher: Royal Society of Chemistry
Citation: Aksenov, A.V., Aksenov, D.A., Griaznov, G.D., Aksenov, N.A., Voskressensky, L.G., Rubin, M. Unexpected cyclization of 2-(2-aminophenyl)indoles with nitroalkenes to furnish indolo[3,2-: C] quinolines // Organic and Biomolecular Chemistry. - 2018. - Volume 16. - Issue 23. - Pages 4325-4332
Series/Report no.: Organic and Biomolecular Chemistry
Abstract: The polyphosphoric acid-mediated reaction of 2-(2-aminophenyl)indenes with nitroalkenes was tested in the frame of synthetic studies towards CDK inhibitors with the paullone core. Unexpectedly, this reaction proceeded via a different mechanistic pathway affording derivatives of the natural alkaloid isocryptolepine. The scope of this unusual transformation was investigated and a mechanistic rationale explaining this outcome is offered
URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-85048659764&origin=resultslist&sort=plf-f&src=s&nlo=&nlr=&nls=&sid=91fa45a4f686626d1b5858a2082471eb&sot=aff&sdt=sisr&sl=145&s=AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29+OR+AF-ID%28%22%5bNo+Affiliation+ID+found%5d%22+60070961%29+OR+AF-ID%28%22%5bNo+Affiliation+ID+found%5d%22+60026323%29&ref=%28Unexpected+cyclization+of+2%29&relpos=2&citeCnt=0&searchTerm=
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