Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12258/2977
Title: Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes
Authors: Aksenov, A. V.
Аксенов, А. В.
Ovcharov, D. S.
Овчаров, Д. С.
Aksenov, N. A.
Аксенов, Н. А.
Aksenov, D. A.
Аксенов, Д. А.
Nadein, O. N.
Надеин, О. Н.
Rubin, M. A.
Рубин, М. А.
Keywords: Aerobic treatment;Aromatic amines;Dual role;Efficient synthesis;Nitroalkanes;Polyphosphoric acids;Selective assembly;Synthetic methods
Issue Date: 2017
Publisher: Royal Society of Chemistry
Citation: Aksenov, A.V., Ovcharov, D.S., Aksenov, N.A., Aksenov, D.A., Nadein, O.N., Rubin, M. Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes // RSC Advances. - 2017. - Volume 7. - Issue 48. - Pages 29927-29932
Series/Report no.: RSC Advances
Abstract: A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and efficient oxidants promoting aromatization of the final product and allowing for the exclusion of a poorly controllable aerobic treatment
URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-85021670891&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=506f935bdae2bbaa7c691f3dc6d28b92&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Dual+role+of+polyphosphoric+acid-activated+nitroalkanes+in+oxidative+peri+-annulations%3a+Efficient+synthesis+of+1%2c3%2c6%2c8-tetraazapyrenes%29&relpos=1&citeCnt=1&searchTerm=
http://hdl.handle.net/20.500.12258/2977
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