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Title: | Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes |
Authors: | Aksenov, A. V. Аксенов, А. В. Ovcharov, D. S. Овчаров, Д. С. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Nadein, O. N. Надеин, О. Н. Rubin, M. A. Рубин, М. А. |
Keywords: | Aerobic treatment;Aromatic amines;Dual role;Efficient synthesis;Nitroalkanes;Polyphosphoric acids;Selective assembly;Synthetic methods |
Issue Date: | 2017 |
Publisher: | Royal Society of Chemistry |
Citation: | Aksenov, A.V., Ovcharov, D.S., Aksenov, N.A., Aksenov, D.A., Nadein, O.N., Rubin, M. Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes // RSC Advances. - 2017. - Volume 7. - Issue 48. - Pages 29927-29932 |
Series/Report no.: | RSC Advances |
Abstract: | A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and efficient oxidants promoting aromatization of the final product and allowing for the exclusion of a poorly controllable aerobic treatment |
URI: | https://www.scopus.com/record/display.uri?eid=2-s2.0-85021670891&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=506f935bdae2bbaa7c691f3dc6d28b92&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Dual+role+of+polyphosphoric+acid-activated+nitroalkanes+in+oxidative+peri+-annulations%3a+Efficient+synthesis+of+1%2c3%2c6%2c8-tetraazapyrenes%29&relpos=1&citeCnt=1&searchTerm= http://hdl.handle.net/20.500.12258/2977 |
Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
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scopusresults 269 .pdf Restricted Access | 62.03 kB | Adobe PDF | View/Open | |
WoS 143 .pdf Restricted Access | 660.29 kB | Adobe PDF | View/Open |
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