Репозиторий научных и учебно-методических публикаций
Северо-Кавказский федеральный университет
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https://dspace.ncfu.ru/handle/20.500.12258/2977| Title: | Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes |
| Authors: | Aksenov, A. V. Аксенов, А. В. Ovcharov, D. S. Овчаров, Д. С. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Nadein, O. N. Надеин, О. Н. Rubin, M. A. Рубин, М. А. |
| Keywords: | Aerobic treatment;Aromatic amines;Dual role;Efficient synthesis;Nitroalkanes;Polyphosphoric acids;Selective assembly;Synthetic methods |
| Issue Date: | 2017 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Aksenov, A.V., Ovcharov, D.S., Aksenov, N.A., Aksenov, D.A., Nadein, O.N., Rubin, M. Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes // RSC Advances. - 2017. - Volume 7. - Issue 48. - Pages 29927-29932 |
| Series/Report no.: | RSC Advances |
| Abstract: | A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and efficient oxidants promoting aromatization of the final product and allowing for the exclusion of a poorly controllable aerobic treatment |
| URI: | http://hdl.handle.net/20.500.12258/2977 |
| Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| scopusresults 269 .pdf Restricted Access | 62.03 kB | Adobe PDF | View/Open | |
| WoS 143 .pdf Restricted Access | 44.45 kB | Adobe PDF | View/Open |
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