Репозиторий научных и учебно-методических публикаций
Северо-Кавказский федеральный университет
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https://dspace.ncfu.ru/handle/20.500.12258/395| Title: | Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes |
| Authors: | Aksenov, N. A. Аксенов, Н. А. Rubin, M. A. Рубин, М. А. |
| Keywords: | Addition reaction;Scaffolds;Carboxamides;Cyclopropene;Nucleophilic addition;Nucleophilic substitutions;Reaction intermediate |
| Issue Date: | 2018 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Maslivetc, V., Barrett, C., Aksenov, N.A., Rubina, M., Rubin, M. Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes // Organic and Biomolecular Chemistry. - 2018. - Volume 16. - Issue 2. - pp. 285-294. |
| Series/Report no.: | Organic and Biomolecular Chemistry |
| Abstract: | An unusual reaction is described, involving a formal intramolecular nucleophilic substitution of bromocyclopropanes with nitrogen ylides generated in situ from N-benzyl carboxamides. It is shown that this reaction involves cyclopropene intermediates and allows for the facile and expeditious preparation of 3-azabicyclo[3.1.0]hexan-2-one scaffolds |
| URI: | https://dspace.ncfu.ru:443/handle/20.500.12258/395 |
| Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| scopusresults (56).pdf Restricted Access | 61.64 kB | Adobe PDF | View/Open | |
| WoS 16 .pdf Restricted Access | 78.2 kB | Adobe PDF | View/Open |
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