Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12258/395
Title: Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes
Authors: Aksenov, N. A.
Аксенов, Н. А.
Rubin, M. A.
Рубин, М. А.
Keywords: Addition reaction;Scaffolds;Carboxamides;Cyclopropene;Nucleophilic addition;Nucleophilic substitutions;Reaction intermediate
Issue Date: 2018
Publisher: Royal Society of Chemistry
Citation: Maslivetc, V., Barrett, C., Aksenov, N.A., Rubina, M., Rubin, M. Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes // Organic and Biomolecular Chemistry. - 2018. - Volume 16. - Issue 2. - pp. 285-294.
Series/Report no.: Organic and Biomolecular Chemistry
Abstract: An unusual reaction is described, involving a formal intramolecular nucleophilic substitution of bromocyclopropanes with nitrogen ylides generated in situ from N-benzyl carboxamides. It is shown that this reaction involves cyclopropene intermediates and allows for the facile and expeditious preparation of 3-azabicyclo[3.1.0]hexan-2-one scaffolds
URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-85040323559&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=nort*+caucas*+fed*+univ*&sid=ebf9446ddab8c0101772b7f698064ac5&sot=afnl&sdt=afsp&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=55&citeCnt=1&searchTerm=
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