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Title: Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes
Authors: Aksenov, N. A.
Аксенов, Н. А.
Rubin, M. A.
Рубин, М. А.
Keywords: Addition reaction;Scaffolds;Carboxamides;Cyclopropene;Nucleophilic addition;Nucleophilic substitutions;Reaction intermediate
Issue Date: 2018
Publisher: Royal Society of Chemistry
Citation: Maslivetc, V., Barrett, C., Aksenov, N.A., Rubina, M., Rubin, M. Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes // Organic and Biomolecular Chemistry. - 2018. - Volume 16. - Issue 2. - pp. 285-294.
Series/Report no.: Organic and Biomolecular Chemistry
Abstract: An unusual reaction is described, involving a formal intramolecular nucleophilic substitution of bromocyclopropanes with nitrogen ylides generated in situ from N-benzyl carboxamides. It is shown that this reaction involves cyclopropene intermediates and allows for the facile and expeditious preparation of 3-azabicyclo[3.1.0]hexan-2-one scaffolds
Appears in Collections:Статьи, проиндексированные в SCOPUS, WOS

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