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DC Field | Value | Language |
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dc.contributor.author | Aksenov, A. V. | - |
dc.contributor.author | Аксенов, А. В. | - |
dc.contributor.author | Smirnov, A. N. | - |
dc.contributor.author | Смирнов, А. Н. | - |
dc.contributor.author | Aksenov, N. A. | - |
dc.contributor.author | Аксенов, Н. А. | - |
dc.contributor.author | Aksenova, I. V. | - |
dc.contributor.author | Аксенова, И. В. | - |
dc.contributor.author | Rubin, M. A. | - |
dc.contributor.author | Рубин, М. А. | - |
dc.date.accessioned | 2019-02-11T12:23:38Z | - |
dc.date.available | 2019-02-11T12:23:38Z | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | Aksenov, A.V., Smirnov, A.N., Aksenov, N.A., Aksenova, I.V., Matheny, J.P., Rubin, M. Metal-free ring expansion of indoles with nitroalkenes: A simple, modular approach to 3-substituted 2-quinolones // RSC Advances. - 2015. - Volume 5. - Issue 12. - Pages 8647-8656 | ru |
dc.identifier.uri | https://www.scopus.com/record/display.uri?eid=2-s2.0-84921311817&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=3a73d74600efaa7e503fb84a84113fb0&sot=afnl&sdt=sisr&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Metal-free+ring+expansion+of+indoles+with+nitroalkenes%3a+A+simple%2c+modular+approach+to+3-substituted+2-quinolones%29&relpos=4&citeCnt=23&searchTerm= | - |
dc.identifier.uri | http://hdl.handle.net/20.500.12258/4247 | - |
dc.description.abstract | 3-Substituted 2-quinolones are obtained via a novel metal-free transannulation reaction of 2-nitroolefins with 2-substituted indoles in polyphosphoric acid. This acid-mediated cascade transformation operates via the ANRORC (Addition of Nucleophile, Ring Opening, and Ring Closure) mechanism and can be used in combination with the Fisher indole synthesis to offer a practical three-component hetero-annulation approach to 2-quinolones from arylhydrazines, 2-nitroalkenes, and acetophenone. An alternative entry to this chemistry employing the alkylation of electron-rich arenes and hetarenes with 1-(2-indolyl)-2-nitroalkene has also been demonstrated | ru |
dc.language.iso | en | ru |
dc.publisher | Royal Society of Chemistry | ru |
dc.relation.ispartofseries | RSC Advances | - |
dc.subject | Ketones | ru |
dc.subject | Arylhydrazines | ru |
dc.subject | Cascade transformations | ru |
dc.subject | Electron-rich arenes | ru |
dc.subject | Modular approach | ru |
dc.subject | Polyphosphoric acids | ru |
dc.subject | Ring expansion | ru |
dc.subject | Synthesis (chemical) | ru |
dc.title | Metal-free ring expansion of indoles with nitroalkenes: A simple, modular approach to 3-substituted 2-quinolones | ru |
dc.type | Статья | ru |
vkr.amount | Pages 8647-8656 | ru |
vkr.inst | Институт математики и естественных наук | - |
Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
Files in This Item:
File | Description | Size | Format | |
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scopusresults 793 .pdf Restricted Access | 64.46 kB | Adobe PDF | View/Open | |
WoS 513 .pdf Restricted Access | 767.46 kB | Adobe PDF | View/Open |
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