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Title: | SNH Alkyl carbamoyl amination of 3-nitropyridine: competitive synthesis of nitro- and nitrosopyridine derivatives |
Authors: | Avakyan, E. K. Авакян, Е. К. Borovlev, I. V. Боровлев, И. В. Demidov, O. P. Демидов, О. П. Amangasieva, G. A. Амангазиева, Г. А. Pobedinskaya, D. Y. Побединская, Д. Ю. |
Keywords: | 3-nitropyridine;SN H alkyl carbamoyl amination;SN H methodology;Ureas |
Issue Date: | 2017 |
Publisher: | Springer New York LLC |
Citation: | Avakyan, E.K., Borovlev, I.V., Demidov, O.P., Amangasieva, G.A., Pobedinskaya, D.Y. S N H Alkyl carbamoyl amination of 3-nitropyridine: competitive synthesis of nitro- and nitrosopyridine derivatives // Chemistry of Heterocyclic Compounds. - 2017. - Volume 53. - Issue 11. - pp. 1207-1213. |
Series/Report no.: | Chemistry of Heterocyclic Compounds |
Abstract: | A method has been developed for oxidative SN H alkyl carbamoyl amination of 3-nitropyridine in anhydrous DMSO. When anions of alkyl- and 1,1-dialkylureas were used as nucleophiles, an unusual formation of a mixture consisting of 1-alkyl(1,1-dialkyl)-3-(5-nitropyridin-2-yl)ureas and their nitroso analogs occurred, which was the first such observation with 3-nitropyridine. Only the nitro products formed in the presence of nitrobenzene. Additionally, a range of N-oxides were obtained on the basis of the synthesized compounds |
URI: | https://www.scopus.com/record/display.uri?eid=2-s2.0-85040080411&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=nort*+caucas*+fed*+univ*&sid=d5d8a0d301244722be90437f5b553481&sot=afnl&sdt=cl&cluster=scopubyr%2c%222017%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=13&citeCnt=0&searchTerm= https://dspace.ncfu.ru:443/handle/20.500.12258/531 |
Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
Files in This Item:
File | Description | Size | Format | |
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scopusresults (77).pdf Restricted Access | 62.75 kB | Adobe PDF | View/Open | |
WoS 45 .pdf Restricted Access | 79.12 kB | Adobe PDF | View/Open |
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