Репозиторий научных и учебно-методических публикаций
ФГАОУ ВО «Северо-Кавказский федеральный университет»
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https://dspace.ncfu.ru/handle/20.500.12258/539| Title: | Regiodivergent condensation of 5-alkoxycarbonyl-1H-pyrrol-2, 3-diones with cyclic ketazinones en route to spirocyclic scaffolds |
| Authors: | Rubin, M. A. Рубин, М. А. |
| Keywords: | Nitrogen heterocycles;Oxygen heterocycles;Pyrrolediones;Spiro compounds;Synthetic methods |
| Issue Date: | 2017 |
| Publisher: | Beilstein-Institut Zur Forderung der Chemischen Wissenschaften |
| Citation: | Dubovtsev, A.Yu., Dmitriev, M.V., Maslivets, A.N., Rubin, M. Regiodivergent condensation of 5-alkoxycarbonyl-1H-pyrrol-2, 3-diones with cyclic ketazinones en route to spirocyclic scaffolds // Beilstein Journal of Organic Chemistry. - 2017. - Volume 13. - pp. 2179-2185. |
| Series/Report no.: | Beilstein Journal of Organic Chemistry |
| Abstract: | The condensation of 5-alkoxycarbonyl-1H-pyrrolediones with cyclic ketazinones was systematically investigated. It was discovered that the regioselectivity of this reaction can be easily swapped between two alternative directions affording derivatives of partially hydrogenated indole or benzofurane. The control of this regioselectivity is efficiently governed by steric effects at the hydrazone moiety of the ketazinone reagent |
| URI: | https://www.scopus.com/record/display.uri?eid=2-s2.0-85033587113&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=nort*+caucas*+fed*+univ*&sid=d5d8a0d301244722be90437f5b553481&sot=afnl&sdt=cl&cluster=scopubyr%2c%222017%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=21&citeCnt=0&searchTerm= https://dspace.ncfu.ru:443/handle/20.500.12258/539 |
| Appears in Collections: | Статьи, проиндексированные в SCOPUS, WOS |
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| scopusresults (83).pdf Restricted Access | 62.99 kB | Adobe PDF | View/Open | |
| WoS 51 .pdf Restricted Access | 3.29 MB | Adobe PDF | View/Open |
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