Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12258/539
Title: Regiodivergent condensation of 5-alkoxycarbonyl-1H-pyrrol-2, 3-diones with cyclic ketazinones en route to spirocyclic scaffolds
Authors: Rubin, M. A.
Рубин, М. А.
Keywords: Nitrogen heterocycles;Oxygen heterocycles;Pyrrolediones;Spiro compounds;Synthetic methods
Issue Date: 2017
Publisher: Beilstein-Institut Zur Forderung der Chemischen Wissenschaften
Citation: Dubovtsev, A.Yu., Dmitriev, M.V., Maslivets, A.N., Rubin, M. Regiodivergent condensation of 5-alkoxycarbonyl-1H-pyrrol-2, 3-diones with cyclic ketazinones en route to spirocyclic scaffolds // Beilstein Journal of Organic Chemistry. - 2017. - Volume 13. - pp. 2179-2185.
Series/Report no.: Beilstein Journal of Organic Chemistry
Abstract: The condensation of 5-alkoxycarbonyl-1H-pyrrolediones with cyclic ketazinones was systematically investigated. It was discovered that the regioselectivity of this reaction can be easily swapped between two alternative directions affording derivatives of partially hydrogenated indole or benzofurane. The control of this regioselectivity is efficiently governed by steric effects at the hydrazone moiety of the ketazinone reagent
URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-85033587113&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=nort*+caucas*+fed*+univ*&sid=d5d8a0d301244722be90437f5b553481&sot=afnl&sdt=cl&cluster=scopubyr%2c%222017%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=21&citeCnt=0&searchTerm=
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