Synthesis of Acylaminoperimidines by the Reaction of 1,8-Naphthylenediamine with Nitroketones

Please use this identifier to cite or link to this item: https://dspace.ncfu.ru/handle/123456789/32959

Title:	Synthesis of Acylaminoperimidines by the Reaction of 1,8-Naphthylenediamine with Nitroketones
Authors:	Aksenov, A. V. Аксенов, А. В. Grishin, I. Y. Гришин, И. Ю. Malyuga, V. V. Малюга, В. В. Aksenov, D. A. Аксенов, Д. А. Dzhioeva, R. G. Джиоева, Р. Г. Aksenov, N. A. Аксенов, Н. А.
Keywords:	Acylamination;Acylation;Heterocyclization;Nitroalkanes;Nitroketones;Polyphosphoric acid
Issue Date:	2026
Publisher:	Pleiades Publishing
Citation:	Aksenov A. V., Grishin I. Y., Malyuga V. V., Aksenov D. A., Dzhioeva R. G., Aksenov N. A. Synthesis of Acylaminoperimidines by the Reaction of 1,8-Naphthylenediamine with Nitroketones // Russian Journal of General Chemistry. - 2026. - 96 (2). - art. no. 12. - DOI: 10.1134/S1070363225606957
Series/Report no.:	Russian Journal of General Chemistry
Abstract:	The reaction of 1,8-naphthylenediamine with α-nitoketones yielded 9-acetyl- and 6(7)-acetamidoperimidines. The reaction exhibits high atom economy and is based on a tandem of benzoylation reactions of the diamine involving nitoketones, and an acylation-amination of arenes in polyphosphoric acid (PPA) medium, using the acyl forms of nitroalkanes liberated in the first stage. The dependence of the transformation’s course on the concentration of polyphosphoric acid has been investigated.
URI:	https://dspace.ncfu.ru/handle/123456789/32959
Appears in Collections:	Статьи, проиндексированные в SCOPUS, WOS

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