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Title: Direct conversion of 3-(2-nitroethyl)-1H-indoles into 2-(1H-indol-2-yl)acetonitriles
Authors: Aksenov, A. V.
Аксенов, А. В.
Aksenov, N. A.
Аксенов, Н. А.
Aleksandrova, E. V.
Александрова, Е. В.
Aksenov, D. A.
Аксенов, Д. А.
Grishin, I. Y.
Гришин, И. Ю.
Rubin, M. A.
Рубин, М. А.
Keywords: Nitroalkanes;Cascade transformations;Heterocycles;1,2-alkyl shift;Rearrangements
Issue Date: 2021
Publisher: MDPI
Citation: Aksenov, A.V., Aksenov, N.A., Aleksandrova, E.V., Aksenov, D.A., Grishin, I.Yu., Sorokina, E.A., Wenger, A., Rubin, M. Direct conversion of 3-(2-nitroethyl)-1H-indoles into 2-(1H-indol-2-yl)acetonitriles // Molecules, - 2021. - Том 26. - Выпуск 20. - Номер статьи 6132. - DOI: 10.3390/molecules26206132
Series/Report no.: Molecules
Abstract: The recently discovered [4+1]-spirocyclization of nitroalkenes to indoles provided a convenient new approach to 2-(1H-indol-2-yl)acetonitriles. However, this reaction was complicated by the formation of inert 3-(2-nitroethyl)-1H-indole byproducts. Herein, we offer a workaround this problem that allows for effective transformation of the unwanted byproducts into acetonitrile target molecules.
Appears in Collections:Статьи, проиндексированные в SCOPUS, WOS

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